Safety Data P O

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SAFETY DATA SHEET FILE NUMBER: 2284

NAME OF PRODUCT ROAD OIL SC-800

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ROAD OIL SC-800

SYNONYMS: PETROLEUM HYDROCARBON

PRODUCT CODE: 2284

MANUFACTURER: SAN JOAQUIN REFINING CO., INC

DIVISION: BAKERSFIELD

ADDRESS: P.O. BOX 5576, BAKERSFIELD, CA., 93388

EMERGENCY PHONE: 661-***-****

RECOMMENDED USE: ROAD PAVING OR OTHER ASPHALT RELATED APPLICATIONS RESTRICTIONS ON USE: NOT TO BE USED FOR PURPOSES OTHER THAN RECOMMENDED USE PREPARED BY: SAN JOAQUIN REFINING CO., INC. HEALTH, SAFETY AND ENVIRONMENTAL DEPARTMENTS SECTION 2: HAZARDS IDENTIFICATION

MATERIAL HAZARD EVALUATION

(Per OSHA Hazard Communication Standard [29 CFR 1910.1200]) Health Precautions: WARNING: Fumes from hot product may cause irritation to the skin, nose, throat and lungs. Hot asphalt may give off hydrogen sulfide (H2S) gas. At elevated concentrations, H2S acts as a systemic poison and causes unconsciousness and death by respiratory paralysis.

Safety Precautions: WARNING: Hot asphalt can cause burns. If burned by hot product, cool affected area immediately with cool water. Do not attempt to remove asphalt from skin. Seek medical attention immediately.

ROUTES OF

ENTRY:

EYES: Yes SKIN: Yes INGESTION: Yes INHALATION: Yes OSHA Hazard: irritant, carcinogen

Signal word: Warning Signal word: Warning Serious eye irritation = GHS Cat. 2 GHS Classification: 2 GHS Classification: 2 Suspected human carcinogen = GHS Cat. 2 HEALTH HAZARDS (ACUTE AND CHRONIC):

EYES: The cool semi-solid material is not expected to cause eye irritation. Thermal burns may result from contact with hot material. Some asphalts, when heated, may produce hydrogen sulfide gas (H2S) (CAS No. 7783-06-4), which is a severe eye irritant. See Section 8 for exposure controls.

SKIN: The cool semi-solid material is not expected to cause skin irritation. Thermal burns may result from contact with hot material. NIOSH states that asphalt fumes or vapors can be absorbed through the skin.

INGESTION: This product may be harmful or fatal if swallowed. May cause dizziness, lack of coordination, headache, nausea and vomiting. Do not induce vomiting, call a physician. INHALATION: Fumes from hot products may be unpleasant and may irritate the upper and lower respiratory tracts. Remove the person to fresh air if respiratory discomfort occurs. Some asphalts, when heated, may give off hydrogen sulfide gas (H2S) (CAS No. 7783-06-4), which is a poison by inhalation and a severe irritant to the nose and throat. See Section 8 for exposure controls. SIGNS AND SYMPTOMS OF EXPOSURE:

EYES: Burns, irritation, redness or blurred vision SKIN: Burns, irritation, redness and inflammation

INGESTION: Dizziness, lack of coordination, headache, nausea or vomiting. Do not induce vomiting. INHALATION: Asphalt fumes may cause nose and throat irritation, coughing, wheezing or shortness of breath, nausea, headaches, stomach pain, decreased appetite or fatigue. 2 of 5

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MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Persons with preexisting skin or respiratory disorders may have their conditions aggravated by overexposure to this material.

SECTION 3: COMPOSITION/ INFORMATION ON INGREDIENTS CHEMICAL FAMILY: PETROLEUM HYDROCARBON

COMPONENT(S) % BY

WEIGHT

Petroleum Asphalt CAS No. 8052-42-4

>70

Gas Oil Petroleum CAS No. 64741-43-1

<25

Petroleum Distillate CAS No. 64741-52-2 <10

Heavy Naphthenic Extract CAS No. 64742-11-6

(Petroleum)

<10

SECTION 4: FIRST AID MEASURES

EYES: Immediately flush eyes with water for a minimum of 15 minutes. Seek medical attention immediately.

SKIN: If hot material is splashed on the skin, immediately drench or immerse the area in water. If available, apply ice water, ice packs (avoid hypothermia) or a water gel blanket on the affected area. Do not try to remove the asphalt from the skin once it has cooled and do not use solvents or thinners to remove the asphalt from the skin. Seek medical attention immediately. Medical personnel can soften and remove the cooled asphalt from the skin by using petroleum jelly or mineral oil.

INGESTION: Do not induce vomiting. If ingested, seek medical attention. INHALATION: If operating conditions create airborne concentrations that exceed the exposure standard, move the person to fresh air. Administer CPR if required. Provide oxygen if breathing is difficult. Seek medical attention immediately.

SECTION 5: FIREFIGHTING MEASURES

FLAMMABLE LIMITS IN AIR, UPPER: No data available

(% BY VOLUME) LOWER: No data available

FLASH POINT: COC ºF: 260º Minimum

EXTINGUISHING MEDIA: Foam, water fog, dry chemical, CO SPECIAL FIRE FIGHTING PROCEDURES: Do not enter confined fire space without proper protective equipment including self-contained breathing apparatus. See Hazardous Decomposition Products. Water or foam may cause frothing. Use of water on asphalt above 100º C (212º F) can cause product to expand with explosive force.

HAZARDOUS DECOMPOSITION PRODUCTS: Normal combustion forms carbon dioxide and water vapor, and may produce oxides of sulfur and nitrogen. Incomplete combustion can produce carbon monoxide.

SECTION 6: ACCIDENTAL RELEASE MEASURES

PERSONAL PROTECTION: Wear safety glasses, rubber gloves, Tyvek type coveralls and rubber boots.

ACCIDENTAL RELEASE MEASURES: In case of spill, clean up using absorbent material such as earth or sand.

RCRA HAZARD CLASS: This product is not a characteristic hazardous waste under RCRA. No EPA waste numbers are applicable for this product’s components. 3 of 5

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SECTION 7: HANDLING AND STORAGE

PERSONAL PROTECTION: Wear safety glasses, rubber gloves, Tyvek type coveralls and rubber boots. HANDLING AND STORAGE: Liquid asphalt is extremely hot. To avoid serious burns, always use the following precautions. Never expose bare skin. Wear a long sleeve cotton shirt, a full face shield, safety goggles and heavy duty gloves which extend up the arm past the shirt cuff. NIOSH and ACGIH recommend keeping asphalt temperatures as low as possible. NIOSH advises use of engineering controls and good work practices at all work sites to minimize worker exposure to asphalt fumes. Some asphalts, when heated, may give off hydrogen sulfide gas (H2S). See Section 8 for exposure controls.

VENTILATION: Use adequate ventilation to keep the airborne concentrations of this material below the established exposure limits.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

COMPONENT(S) CAL-OSHA

PEL- TWA

(8 HOUR)

ACGIH TLV-TWA

(8 HOUR)

OTHER LIMITS

RECOMMENDED

Petroleum Asphalt CAS No. 8052-42-4

5 mg/m 0.5 mg/m

(as the inhalable

fraction)

NIOSH REL

5 mg/m

(15 Minute)

Gas Oil Petroleum CAS No. 64741-43-1

5 mg/m 5 mg/m

(as oil mist)

None

Petroleum Distillate CAS No. 64741-52-2 5 mg/m 5 mg/m

(as oil mist)

None

Heavy Naphthenic Extract CAS No. 64742-11-6

(Petroleum)

5 mg/m 5 mg/m

(as oil mist)

None

RESPIRATORY PROTECTION: If operating conditions create airborne concentrations that exceed the exposure standard for asphalt fumes, the use of an approved NIOSH/OSHA respirator for organic vapors or air supplied breathing equipment is recommended. Hydrogen Sulfide Exposure Limit:

ACGIH: (1PPM) TLV-TWA

(5PPM) TLV-STEL

CAL-OSHA: 10PPM / (14 mg/m of air)– PEL

15PPM / (21 mg/m of air) – STEL

50PPM - ceiling

EYE PROTECTION: Wear appropriate safety glasses, goggles or full face shield. SKIN PROTECTION: Long sleeve cotton shirt and cotton pants are recommended. Wear appropriate gloves.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Black Liquid UPPER/LOWER FLAM/EXP LMT: NDA ODOR: Little or no odor VAPOR PRESSURE (mmHg): 0.5 ODOR THRESHHOLD: NDA VAPOR DENSITY (AIR = 1): NA

pH: NDA RELATIVE DENSITY: NDA

MELTING/FREEZING PT: NDA SOLUBILITY IN WATER: NIL

INITIAL BOILING POINT: @760º mmHg: 300º F PART. COEF. N-OCT/H2O 10 FLASH POINT: COC ºF: 260º Minimum AUTOIGNITION TEMP: NDA EVAPORATION RATE (ETHYL ETHER = 1): NA DECOMPOSITION TEMP: NDA FLAMMABILITY (solid, gas): NDA SPECIFIC GRAVITY (H2O = 1): .97 PERCENT VOLATILE (% BY VOL.): NA

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SECTION 10: STABILITY AND REACTIVITY

STABILITY: Stable

CONDITIONS CONTRIBUTING TO INSTABILITY: None

INCOMPATIBILITY (MATERIAL TO AVOID): May react with strong oxidizers. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Normal combustion forms carbon dioxide and water vapor, and may produce oxides of sulfur and nitrogen. Incomplete combustion can produce carbon monoxide.

HAZARDOUS POLYMERIZATION: Will not occur

SECTION 11: TOXICOLOGICAL INFORMATION

CARCINOGENICITY:

ACGIH, NTP, OSHA and IARC carcinogen lists were checked for those components with CAS Registry Numbers (8052-42-4), (64741-43-1), (64741-52-2) and (64742-11-6). ACGIH: Asphalt fumes (coal tar-free) are designated as A4 – NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.

IARC: Bitumens – during road paving the occupational exposures to bitumens and their emissions have been assigned a Group 2B (“possibly carcinogenic to humans”) classification. Gas Oil (petroleum) is not listed

Distillates (petroleum), heavy naphthenic unrefined or mildly refined baseoil and Extracts,

(petroleum), heavy naphthenic distillate solvent are categorized by the International Agency for Research on Cancer as causing skin cancer in laboratory animals when the oil was repeatedly applied for most of the lifetime of the animal with no effort made to remove the oil between applications. Handling instructions and precautions outlined in this MSDS should be followed when handling this product.

NTP: Asphalt fumes are not listed as a known or reasonably anticipated human carcinogen. OSHA: Asphalt fumes are not classified as carcinogens. SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICITY: Asphalt is not expected to cause acute or chronic toxicity to aquatic organisms due to the extremely low water solubility of this material. PERSISTENCE & DEGRADABILITY: Although component hydrocarbons may undergo direct or indirect photo degradation, the physiochemical characteristics of asphalt under ambient conditions will not facilitate these reactions. BIOACCUMULATIVE POTENTIAL: NDA

MOBILITY IN SOIL: NDA

OTHER ADVERSE EFFECTS: NDA

AQUATIC RELEASE: Advise authorities if product has entered or may enter watercourses or sewer drains.

SECTION 13: DISPOSAL CONSIDERATIONS

WASTE RESIDUES DESCRIPTION: This product is not a characteristic hazardous waste under RCRA. No EPA waste numbers are applicable for this product’s components. SAFE HANDLING INFORMATION: See Section 7 (Handling and Storage) WASTE DISPOSAL METHOD: Observe Federal, State and Local regulations covering chemical waste spills.

SECTION 14: TRANSPORT INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION:

PROPER SHIPPING NAME: ELEVATED TEMPERATURE LIQUID, N.O.S. (CUTBACK ASPHALT) HAZARD CLASS: 9 PACKING GROUP: III

ID NUMBER: UN3257 REQUIRED LABEL(S): CLASS 9

BASIC DESCRIPTION: UN3257, ELEVATED TEMPERATURE LIQUID, N.O.S. (CUTBACK ASPHALT), 9, PGIII AMBIENT TEMPERATURE MATERIAL (SOLID)

PROPER SHIPPING NAME: Not regulate by D.O.T.

HAZARD CLASS: None ID NUMBER: None D.O.T. SHIPPING LABEL: Not regulated by D.O.T. 5 of 5

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SECTION 15: REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS:

TSCA (TOXIC SUBSTANCE CONTROL ACT) REGISTRY: Listed CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT): Asphalt is not a hazardous substance under CERCLA. SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): 302/304 Asphalt is a hazardous chemical under 40 CFR Part 355. Asphalt is not listed as an extremely hazardous substance in 40 CFR Part 355, and is not known to contain an extremely hazardous substance in a concentration greater than one percent by weight. 311/312 HAZARD CATEGORIES: Acute Health Hazard: Yes Chronic Health Hazard: Yes

Fire Hazard: No

Pressure Release Hazard: No

Reactivity Hazard: No

313 This product is not known to contain any components in concentrations above OSHA de minimus levels that are listed as toxic in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA.

WHMIS: Listed

OSHA: 29 CFR 1910.1200 (Hazard Communication) required STATE REGULATIONS:

CALIFORNIA PROPOSITION 65 (The Safe Drinking Water and Toxics Enforcement Act) WARNING: This product can expose you to chemicals including toluene, which is known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.

Asphalt or asphalt fumes appear on one or more of the hazardous substances lists in the following states:

CA FL HI MA MN NJ PA WA

SECTION 16: OTHER INFORMATION

DATE REVISED: 8/20/18

SUPERCEDES: 12/22/17

The information provided in this Safety Data Sheet is believed to be accurate and reliable on and as of the date on this page. However, this Safety Data Sheet is not a guarantee or warranty of any kind, express or implied. Any and all warranties of merchantability and/or fitness for a particular purpose are specifically disclaimed. It is the user’s responsibility to determine the conditions under which the product is used, including the selection of engineering controls, work practices and Personal Protective Equipment to minimize hazards.

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