Dr. Volodymyr Tsyalkovsky
U.S. Permanent Resident
*** ******** ********* ******** **********, Center for Optical Materials
Science and Engineering Technologies, School of Materials Science and
Engineering, Clemson University, 91 Technology Drive, Anderson, SC 29625
Phone 864-***-**** ( FAX 864-***-**** ( Cell 864-***-**** (
E-mail *******@*******.***
http://www.linkedin.com/in/tsyalkovsky
OBJECTIVE
A research career to explore the chemistry of materials and to expedite
the application of the achievements of science to new technologies,
through the synthesis of new materials, characterization and elucidation
of structure/property relationships.
RESEARCH INTERESTS AND EXPERTISE
Organic synthesis: total synthesis of heterocyclic compounds for
biological activity study; methodology research; macromolecular synthesis
(free radical polymerization, ATRP); polymer functionalization; colloidal
synthesis. Polymer films: nanofabrication of thin polymer films; multi-
component polymer systems for advanced applications; polymer/nanoparticles
composites. Organic optoelectronics: semiconductive polymers;
fabrication, emission testing and optimization of organic
electroluminescent devices.
EDUCATION
03/2006 - 10/2007 Postdoc. Polymer Chemistry / Materials Science,
Clemson University, Clemson, SC, USA
05/2006 Ph.D. Organic Chemistry, GPA 4.33/5.00,
Lviv Polytechnic National University, Lviv, Ukraine
06/2001 B.S./M.S. Chemistry, GPA 4.97/5.00 (summa cum laude),
Ivan Franko National University of Lviv, Lviv, Ukraine
PROFESSIONAL EXPERIENCE / EMPLOYMENT
Center for Optical Materials Science and Engineering Technologies, CLEMSON
UNIVERSITY, Clemson, SC
06/2009 - present Research Assistant Professor
Synthesis of polymeric materials for efficient electroluminescent
devices.
Synthesis of polymerizable fluorescent dyes and their incorporation
into polymer chains.
Converting established and novel polymeric systems into colloidal
forms in order to facilitate their printing into operational polymeric
light emitting devices (PLEDs).
11/2007 - 06/2009 Research Associate
Improved PLEDs performance through design, synthesis, and
characterization of charge transporting polymers.
Colloidal synthesis through a mini-emulsion route and an emulsion
polymerization.
Managing and overseeing the synthetic efforts of a number of Ph.D.
candidates.
School of Materials Science and Engineering, CLEMSON UNIVERSITY, Clemson,
SC
03/2006 - 10/2007 Postdoctoral Research Associate
Fabrication and Self-Assembly of Smart Nanoparticles:
Poly(glycidyl methacrylate) was synthesized and fluorescently labeled
with Rhodamine B.
Aforementioned polymer was utilized to form a reactive and fluorescent
shell on nanoparticles.
An ultrahydrophobic textile surface was created utilizing reactive
nanoparticles.
Department of Organic Chemistry, IVAN FRANKO NATIONAL UNIVERSITY OF LVIV,
Lviv, Ukraine
11/2004 - 03/2006 Assistant Professor / Research Associate
Synthesis of heterocyclic systems for biological activity screening:
Investigated the interactions of alkyl 3-aryl-2-bromopropanoates with
binucleophilic reagents.
Created a new type of domino-reaction by combining of Knoevenagel
condensation and hetero-Diels-Alder reaction.
10/2001 - 10/2004 Graduate Research Assistant
Heterocyclizations on the basis of arylation and hetarylation products
of unsaturated compounds:
Created the combinatorial libraries of 2,3,5-trisubstituted 4-
thiazolidinones via the reaction of bromoesters with polyfunctional
thioamides.
Synthesized new derivatives of 1,2,4-thiadiazole and 1,2,4-triazole.
03/2003 - 12/2003 Junior Research Scientist
Created the combinatorial library of 4-thiazolidinones.
07/2001 - 09/2001 Research Engineer
Developed novel protocols for the synthesis of heterocycles from the
products of Meerwein arylation.
PROFESSIONAL AFFILIATIONS
. Member of American Chemical Society, ACS (2007 - present)
. Reviewer for Chemical Communications (RSC, UK), Organic & Biomolecular
Chemistry (RSC, UK), Macromolecular Rapid Communications (Wiley-VCH,
Germany), Langmuir (ACS, USA), Biomacromolecules (ACS, USA), Journal
of Applied Polymer Science (John Wiley & Sons, USA), Polymer
International (Wiley-VCH, Germany), European Polymer Journal
(Elsevier), Surface and Coatings Technology (Elsevier), Applied
Surface Science (Elsevier), Journal of Electron Spectroscopy and
Related Phenomena (Elsevier), Journal of Engineered Fibers and Fabrics
(e-Journal)
HONORS AND AWARDS
. Summa cum laude (GPA 4.97/5.00), Ivan Franko National University of
Lviv (2001).
. Success in Studies, Student Scientific Research and Active
Participation in Civil Life of the University, Ivan Franko National
University of Lviv (2000).
. Scholarship for Excellent Students and Young Scientists provided by
the Ukrainian Diaspora in Canada, Ivan Franko National University of
Lviv (1999).
. Distinguished Student Title, Ivan Franko National University of Lviv
(1996-2001).
. First place in high school Chemistry Olympiad in Lviv City (1996,
1994, 1993).
. Second place in high school Chemistry Olympiad in Lviv City (1995).
. Third place in high school Chemistry Olympiad in Lviv Region (1994,
1993).
APPLIED INSTRUMENTATION AND TECHNIQUES
. Nuclear Magnetic Resonance (JEOL ECX-300, Bruker Avance 300, 300 MHz)
. CHNS/O elemental analysis (2400 Series II CHNS/O Analyzer,
PerkinElmer)
. Photoluminescence spectroscopy (Jobin-Yvon Fluorolog FL-3-22/Tau-3
Spectrofluorometer)
. UV-vis absorption spectroscopy (Perkin Elmer Lambda 850
Spectrophotometer)
. Infrared absorption spectroscopy (Nicolet 560 FTIR Spectrometer)
. Gel Permeation Chromatography (Waters Corp.)
. Thermogravimetric Analysis (TA Instruments)
. Differential Scanning Calorimetry (TA Instruments DSC 2920)
. Atomic Force Microscopy (Dimension 3100 Scanning Probe Microscope,
Veeco Instruments)
. Profilometry (Alpha-Step IQ Surface Profiler, KLA-Tencor Corp.)
. Dynamic Light Scattering (Coulter N4Plus DLS Analyzer)
. Mass spectrometry (Shimadzu GC-17 GC-mass Spectrometer)
. Ellipsometry (COMPEL Automatic Ellipsometer, InOmTech, Inc.)
. Drop contact angle measurements (Contact Angle Goniometer, Kruss,
model DSA10)
. Plasma cleaning; dip coating; spin coating
MISCELLANEOUS
Computer Skills
Windows, MS Office, IE, Adobe products, SciFinder, Web of Science,
EndNote, LaTeX, Origin, ACDLabs, Delta.
Languages
English, Ukrainian (native), Russian, Polish.
Permanent Residency
Since January 2010.
1. Tsyalkovsky, V.; Klep, V.; Ramaratnam, K.; Lupitskyy, R.; Minko, S.;
Luzinov, I. Fluorescent Reactive Core-Shell Composite Nanoparticles
with High Surface Concentration of Epoxy Functionalities. Chemistry of
Materials (2008), 20 (1), 317-325.
2. Ramaratnam, K.; Tsyalkovsky, V.; Klep, V.; Luzinov, I.
Ultrahydrophobic Textile Surface via Decorating Fibers with Monolayer
of Reactive Nanoparticles and Non-Fluorinated Polymer. Chemical
Communications (2007), 43, 4510-4512.
3. Matiichuk, V.S.; Obushak, N.D.; Tsyalkovskii, V.M. Synthesis of
Heterocycles from Arylation Products of Unsaturated Compounds: Part
XIII. 5-R1-Benzyl-2-(R2-2-pyridylimino)thiazolidin-4-ones. Russian
Journal of Organic Chemistry (2005), 41 (7), 1050-1054.
4. Tsyalkovsky, V.M.; Kutsyk, R.V.; Matiychuk, V.S.; Obushak, N.D.;
Klyufinskaya, T.I. Synthesis and Antimicrobial Activity of 5-(R1-
Benzyl)-2-(R2-benzylidenehydrazono)-3-(2-furylmethyl)thiazolidin-4-
ones. Pharmaceutical Chemistry Journal (2005), 39 (5), 245-247.
Curriculum Vitae
Selected Publications