Department of Chemistry
North Carolina Central University
**** **** ****** ******* *******
Durham, North Carolina 27707
Tel: 919-***-**** Fax: 919-***-****
Email: *******@****.***
http://web.nccu.edu/chemistry/staff.php
Curriculum Vitae
Darlene K. Taylor
Personal Information
Born: November 1, 1967; Burlington, North Carolina.
Married: Erwin Taylor since 1993; Children: Mary (8), Justin (5), and Skyler (4).
Education
Ph. D. Physical Polymer Chemistry, University of North Carolina at Chapel Hill; October 1998
Polar Ordering in Rigid to Semi-Flexible Nonlinear Optical Side Chain Polymers
(Advisor: Professor Edward T. Samulski)
M.S. University of North Carolina at Chapel Hill; May 1994
The Mechanism of Coupling in Cyclophane Biradicals (Advisor: Professor M. D. E. Forbes)
M.S. Analytical Chemistry, North Carolina A&T State University, August 1992
A Modified NMR System for Static and On-line Measurements of Polymer Solutions
(Advisors: Dr. H. Lee McPeters and Professor A. Williamson)
B.A. Chemistry, Goucher College; May 1989
Research Positions
2002 2004, Research Associate, University of North Carolina at Chapel Hill.
(Advised by Professor Joseph M. DeSimone)
Utilized attenuated total reflection-Fourier transform infrared spectroscopy to monitor in situ
solution and bulk free radical copolymerizations of methyl methacrylate and fluorinated
methacrylates. Compared this technique to 1H NMR measurements. Determined the reactivity
ratios for these copolymerizations in supercritical carbon dioxide, bulk, and freon.
1999- 2001, Post doctoral Fellow, University of North Carolina at Chapel Hill.
(Advised by Professor Joseph M. DeSimone)
Darlene K. Taylor 2 of 7
Explored association behavior of amphiphilic block copolymers in carbon dioxide by light
scattering and small angle neutron scattering. Determined the mass, size, and interaction
parameter of block copolymers and homopolymers in conventional solvents and carbon dioxide
by light scattering.
1994-1998 Research Assistant, University of North Carolina at Chapel Hill.
Designed novel monomers and developed HPLC purification protocol. Characterized monomer
purity by various spectroscopic techniques including NMR, FTIR, UV-Vis. Polymerized
monomers by step growth polymerizations and characterized by spectroscopic techniques as well
as thermal analysis techniques such as TGA and DSC. Utilized second harmonic generation to
investigate the electric field induced polar order stability of nonlinear optical chromophores
covalently attached as side chains to rigid backbone polymers.
1991-1994 Research Assistant, University of North Carolina at Chapel Hill.
Conducted synthesis and spectroscopic characterization of cyclophanes. Studied biradicals in
solution as function of temperature and radical structure by time-resolved Electron Paramagnetic
Resonance. Modeling studies were utilized to elucidate the mechanism of interaction between the
closely associated biradical end groups.
1990 - 1991 Research Technician, Rohm and Haas Company Norristown, Pennsylvania.
Utilized low resolution NMR as an online process and quality control technique for polymerization
reactions.
Summer 1988, Nova Pharmaceutical Corporation, Baltimore, Maryland,
Isolated and radiolabeled rat brain tissue and screened drugs for receptor activity.
Professional Positions
2002- 2005 RICHES Manager, Science and Technology Center for Environmentally Responsible
Solvents and Processes (CERSP), University of North Carolina at Chapel Hill.
RICHES is an acronym for Reaching Industry, Communities, and Higher Education Students. In
this outreach position, the following objectives were accomplished:
Lead overall outreach efforts to underrepresented groups and women in sciences at higher
education level by leveraging efforts of existing programs
Lead overall outreach efforts (like exhibits, demonstrations, stipends, etc.) to social,
government, and academic communities including leveraging support for this endeavor by
authoring four research proposals funded by NSF ($877K total).
Assumed responsibilities of Technical Coordinator of Center Activities including
coordinating outreach activities to industry.
1999- 2001 Technical Coordinator, University of North Carolina at Chapel Hill.
Responsible for the following duties:
Organized four different semi-annual Kenan Center review meetings that involved
technical presentations of around 50 posters and 10 talks
Conducted over 50 tours of laboratory facilities for industrial and academic professionals
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Designed and edited two editions of Kenan Center News (a bi-annual publication of Kenan
Center for the Utilization of Carbon Dioxide in Manufacturing) as well as one edition of
CERSP News (a yearly publication of the NSF Science and Technology CERSP).
Honors
SC07 Education Program Award (2007)
Dean s Award - Excellence in Research, North Carolina Central University (2007)
Duke/NCCU Stem Partnership Award to facilitate research collaborations at Duke (w/ E. Toone)
on polymeric drug delivery materials (2007-2008).
Faculty Fellow, Computations Science Education Reference Desk, Shodor Organization, (Summer
2006: two weeks)
Scholar in Residence at Rohm and Haas (1990- 1991)
Hoechst Celanese Fellow (1995-1996)
Department of Education Fellow (1993-1994)
Affiliations
Materials Research Society (2005-present)
National Organization of Black Chemists and Chemical Engineers (2006 present)
American Chemical Society (1992-present)
Service
Co-Organizer (w/ Mukhopadhyay), Chemistry Department Seminar Series (2006)
Co-Chairperson (w/ Mukhopadhyay), Chemistry Department Publication/Communication
(2006)
Advisor, Academic counseling for eight undergraduate students (2006)
Moderator, Physical Chemistry Papers presented at Local Section Conference, ACS (2006)
Advisor (w/ S. DeLauder; A. Williams), National Organization of Black Chemists and Chemical
Engineers (2005-present)
Faculty Marshall, NC Central University (2005-2006)
Co-organizer (w/ J.M. DeSimone) of "Green Chemistry and Manufacturing", SERMACS (2004)
Reviewer, National Science Foundation Panel (2005)
Editor, CERSP News (2000 present)
Co-organizer (w/ J.M. DeSimone) of "Green Chemistry and Manufacturing", SERMACS 2004
Teaching/Advising
Students Advised
Current Research Group Members
Student Name Position
Gibson, Melody M.S.
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Koepnick, Brian High School
Past Research Group Members
Student Name Position Current Location
Fouti, Regis Undergraduate unknown
Jackson, Alexander Summer Undergrad NCCU
Karioki, Lee Undergraduate NCCU BRITE
Ukponmwan, Sylvia E. Undergraduate
Miatudila, Mubalutila Undergraduate
CHEM 4010/Physical Chemistry I (4.0) and CHEM 4020/ Physical Chemistry II (4.0)
6 students a year
15 3-hour lectures, 1-hour recitation, and 3-hour laboratory per week
An introduction to fundamental principles of physical chemistry. The first course in this topic
covers gases, chemical thermodynamics, thermochemistry, physical and chemical equilibria,
solutions, and chemical kinetics. The second course covers the theory of quantum mechanics
and its application to chemistry including a survey of various spectroscopic techniques. A
laboratory manual was developed for CHEM 4020 and will be updated for Spring 2007 based on
feedback from the students and experience with the activities. Many of the experiments were
theoretical or computer based adaptation of traditional labs. This was necessary since much of
the equipment and chemicals were not available due to our recent relocation to Mary Townes
Science Complex.
CHEM 4900/ Applied Math (2.0)
6 students a year
15 2-hour lectures per week
The application of calculus and advanced mathematical techniques to physical chemistry. This
course provides many of the skills students need to master the second semester of physical
chemistry (CHEM 4020). Calculus and advanced mathematical techniques are emphasized to
build confidence and familiarity in working with operators, eigenfunctions, matrices, etc.
CHEM 5730/ Chemical Thermodynamics (3.0)
3 students a year
15 3 hour lectures per week
This is a graduate level course taught in two parts: 1) Classical Thermodynamics and 2) Statistical
Thermodynamics. All of the students taking this course were deeply interested in
pharmaceutical/biological research questions. I attempted to augment their appreciation for
thermodynamics by assigning projects that required each student to write and orally present a
proposal that was rooted in thermo principles applied to the drug industry. The reports and
Darlene K. Taylor 5 of 7
presentations were externally reviewed by graduate students in the chemistry department. An
example report and review comments are provided in the appendix.
CHEM 1200L/General Chemistry II Lab (0.0)
48 students a year
15 3-hour laboratory per week
An integrated course of general chemistry and qualitative analysis. A laboratory manual has been
co-developed by me and the lead instructor (Dr. Jim Ellenson).
Presentations
Towards water-soluble star copolymer-drug conjugates. Ibraheem, B.; Mubalutila, M.; Jackson, A.;
Taylor, D. K. Proceedings of 58th Conference of South East Regional American Chemical Society,
August, GA, November 1-4,2006 (invited).
Environmentally Friendly Alternatives for the Dry Cleaning and Printing Industries. Taylor, D. K.;
DeSimone, J. M.; Carbonell, R. G. NSF Workshop on Environmentally Benign Process Research
Needs, Hancock, MA, August 14-16, 2002. (Invited)
Center for Environmentally Responsible Solvents and Processes. exhibit/recruitment booth at
National Organization Black Chemists Chemical Engineers, Baltimore, MD, April 2001.
Self-Assembly of Mixed Micelles in CO2 as Investigated by SANS. Taylor, D. K.; Wells, S.; Yoshia,
E.; Rubenstein, M.; Adam, M.; DeSimone, J. M. PolyMillennial 2000 Conference, Waikoloa, Hawaii,
December 2000.
Investigating the Alignment of Rigid Rod Polymers. Taylor, D. K.; Samulski, E. T. poster presented
at Gordon Conference on Polymers, Ventura, California, January 1997.
Poly(p-phenylene)s with NLO Sidechains. Taylor, D. K.; Samulski, E. T. poster presented at
International Chemical Congress of Pacific Basin Societies, Honolulu, Hawaii, December 1995.
North Carolina A&T State University Chemistry Awards Banquet May 1991(Invited Speaker)
North Carolina A&T State University Chemistry Awards Banquet May 2002 (Invited Speaker).
Publications
(Peer Reviewed)
1. Taylor, D. K.; Skaf, D. W.; Bessel, C. A. Greening Dry Cleaning. J. Chem. Ed., 2007, in revision.
2. Ibrahem, B.; Mubalutila, M.; Jackson, A.; Taylor, D. K. Towards water-soluble star copolymer-
drug conjugates. Proceedings of 58th Conference of South East Regional American Chemical
Society, Augusta, G.A., November 1-5, 2006.
Darlene K. Taylor 6 of 7
3. EXPERT: A multidisciplinary undergraduate program to enhance education and diversity in
science and engineering Bothun, G.; Uitenham, L. C.; DeSimone, J. M.; Baucom, E. I.; Taylor,
D.K., Chem. Eng. Ed. 2006, in revision based on reviews.
4. Andr, P.; Lacroix-Desmazes, P.; Taylor, D. K.; Boutevin, B. Solubility of Fluorinated
Homopolymer and Block Copolymer in Compressed CO2, submitted to J. Supercritical Fluids,
2006, 37, 263-270.
5. Lacroix-Desmazes, P.; Boutevin, B.; Young, J.L.; Taylor, D.K.; DeSimone, J.M. Synthesis and
Characterization of Fluorinated Block Copolymers as Well-Defined Macromolecular Surfactants for
Carbon Dioxide Applications,, Proceedings of 8th Meeting on Supercritical Fluids, International Society for
the Advancement of Supercritical Fluids Bordeaux, France, April 14-17, 2002.
6. Taylor, D. K.; Keiper, J.; DeSimone, J. M. Polymer Self-Assembly in Carbon Dioxide, Ind. Eng. Chem.
Res. 2002, 41, 4451-4459.
7. Wells, S.L.; Taylor, D. ; Adam, M.; DeSimone, J. M.; Farago, B. Study of the Association of a Diblock
Copolymer and Absorption of an Insoluble Homopolymer in CO2, Macromolecules 2001, 34(18), 6161-
6163.
8. Taylor, D. K.; Carbonell, R.; DeSimone, J. M. Opportunities for Pollution Prevention and
Energy Efficiency Enabled by the Carbon Dioxide Technology Platform, Annu. Rev. Energy Environ.
2000, 25, 115-146.
9. Taylor, D. K.; Samulski, E. T. Synthesis and Characterization of Poly(p-phenylene)s with
Nonlinear Optical Side Chains, Macromolecules 2000, 33, 2355-2358.
(Non-peer Reviewed)
10. Taylor, D. K.; DeSimone, J. M. Triple Bottom Line : Building the Carbon Dioxide Technology
Platform Clean Solvent Symposium, Abstracts of Papers of the Amer. Chem. Soc. 220: 71-IEC Part
1 AUG 20 2000.
11. Taylor, D. K.; McPeters, H. L. Polymer Solution Analysis by a Small NMR Spectrometer. in
Proceedings in the 18th Annual Meeting of the National Organization for the Professional
Advancement of Black Chemists and Chemical Engineers, April 1-5, 1991.
Funded Proposals
1. Hyperbranched Polyglycerols as a Therapeutic Platform (PI: DK Taylor)
Agency: Extramural Associates Research Development Award (EARDA), $15,000. Period:
(2006-2007).
2. Investigations of the Synthetic, Structural, and Energetic Properties of Hybrid Inorganic-Oligo(p-
phenylene)s Core-Shell Particles, (PI: DK Taylor)
Agency: ACS Petroleum Research Fund Type: Research Grant Type G, $35,000. Period: 2006-2008.
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3. Chemical Process Development and Property Characterization of New Industry, (Co-PI:
Taylor w/ Resnick)
Agency: Fuxin Heng Tong Fluorine Chemicals Co. Ltd., Type: Contract ; $48,550. Period: 10/06-
06/07
4. "Design and Synthesis of Core-Shell OptoElectronic Nanoparticles," (Co-PI: DK Taylor w/
Roberts)
Agency: ACS PRF; Type: Research Grant Type SRF (Summer Research Fellowship) $8,000.
Period: 5/1/07-8/31/07